Dr. John R. Monnier passed away on April 6, 2024 at the age of 76. John was Professor of Chemical Engineering at the University of South Carolina, which he joined in 2004 after retiring as a Technology Fellow at the Eastman Chemical Company in Kingsport, Tennessee.
John graduated with a bachelor’s degree in chemistry from St. Ambrose College in Davenport, Iowa, and a master’s in Heterogeneous Catalysis at the University of Wisconsin-Milwaukee with Prof. George W. Keulks in the area of catalytic olefin epoxidation, in 1972. Thereafter, John began his professional career in the Corporate Research Laboratories of Eastman Kodak Company in Rochester, NY. He returned to UW-Milwaukee in 1976 on an academic leave of absence and received his Ph.D. in Heterogeneous Catalysis in 1978, again with Prof. Keulks. John resumed his work at Eastman Kodak in Rochester, and transferred in 1993 to Eastman Chemical in Kingsport, where he worked until his retirement from industry.
Dr. Monnier’s study of the epoxidation of higher olefins began in 1986, and culminated in his discovery of a catalyst system which selectively epoxidizes butadiene to 3,4‑epoxybutene using molecular oxygen in the gas phase, which represented the first advancement of olefin epoxidation using molecular oxygen in more than 50 years. This work was recognized in 1988 with the C. E. K. Mees Award, given annually for the most outstanding research conducted at Kodak Research Laboratories. In 1993, he was named Outstanding Researcher for the Northeast Tennessee Division of the American Chemical Society.
Commercialized in 1997, the epoxidation of butadiene, and downstream transformation of epoxybutene, uses several novel catalytic processes, including the isomerization reactions of epoxybutene to 2,5‑dihydrofuran and 2,5‑dihydrofuran to 2,3‑dihydrofuran, as well as the remarkably selective hydrogenation of epoxybutene to epoxybutane. Monnier is either the sole or co-discoverer of each of these reactions, for which he received more than 25 patents.
The accolades for Dr. Monnier’s research and development in epoxidation continued in force. In 1998, he was named Outstanding Industrial Innovator by the American Chemical Society. In 2000, Monnier received the Herman Pines Award from the Chicago Catalysis Club. He was awarded the 2002 Ciapetta Lectureship in Catalysis, one of the four major biennial awards of the North American Catalysis Society.
The progression of John’s physical disability – he had muscular dystrophy – precipitated a move from industry to academia in 2004. At the University of South Carolina in Columbia, SC, John excelled at the new calling of mentoring graduate students, applying his unparalleled combination of industrial relevance, practical knowledge, intense wit, and self-effacing humor. Though in a wheelchair, John’s spirit soared; coming down the hallway his raucous voice was always heard before he was seen.
At USC, John continued his work in epoxidation catalysis, achieving a new understanding of the electronic role of alkali promoters. He developed a new method to synthesize supported bimetallic nanoparticles based on electroless deposition, a process he had seen employed at Kodak on bulk materials, and he continued to refine characterization methods including in-situ x‑ray diffraction and chemisorption. John’s industrial background and expertise in heterogeneous catalyst preparation, characterization, and evaluation lent great credence to USC’s NSF-supported industrial consortium, the Center for Rational Catalyst Synthesis (CeRCaS).
And the national awards did not stop. In 2017, John received the American Institute of Chemical Engineer’s Chemical and Reaction Engineering Practice Award, and most significantly in 2017, Professor Monnier was inducted into the National Academy of Engineering. In 2022, John received the Excellence in Catalysis Award from the Philadelphia Catalysis Society.
In his twenty years at USC, Dr. Monnier advised twenty-two Ph.D. students and numerous visiting scholars, postdocs, and undergraduate students. These mentees and his academic and industrial colleagues and staff will remember John with tremendous affection as a brilliant catalytic scientist whose numerous accomplishments and accolades were always exceeded by his humility and his humanity.
JR Regalbuto
April 11, 2024