Eugene Houdry: Catalytic Cracking of low-grade fuel into gasoline

Eugene Houdry

Eugene Houdry

One of the first improvements in petrochemical production was the process developed by Eugene Houdry for “cracking” petroleum molecules into the shorter ones that constitute gasoline. (Earlier commercial processes for cracking petroleum relied instead on heat.)

Eugene Houdry (1892–1962) obtained a degree in mechanical engineering in his native France before joining the family metalworking business in 1911. After he served in the tank corps in World War I—for which he received honors for extraordinary heroism in battle—he pursued his interest in automobiles (especially race cars) and their engines. On a trip to the United States he visited the Ford Motor Company factory and attended the Indianapolis 500 race. His interest soon narrowed to improved fuels. Because France produced little petroleum—and the world supply was thought to have nearly run out—Houdry, like many other chemists and engineers, searched for a method to make gasoline from France’s plentiful lignite (brown coal). After testing hundreds of catalysts to effect the hoped-for molecular rearrangement, Houdry began working with silica-alumina and changed his feedstock from lignite to heavy liquid tars. By 1930 he had produced small samples of gasoline that showed promise as a motor fuel.

In the early 1930s Houdry collaborated with two American oil companies, Socony Vacuum and Sun Oil, to build pilot plants. Oil companies that did not want to resort to the new additive tetraethyl lead were eagerly looking for other means to increase octane levels in gasoline. In 1937 Sun Oil opened a full-scale Houdry unit at its refinery in Marcus Hook, Pennsylvania, to produce high-octane Nu-Blue Sunoco gasoline. By 1942, 14 Houdry fixed-bed catalytic units were bearing the unanticipated burden of producing high-octane aviation gasoline for the armed forces.

(One limitation of the process was that it deposited coke on the catalyst, which required that the unit be shut down while the coke was burned off in a regeneration cycle. Warren K. Lewis and Edwin R. Gilliland of the Massachusetts Institute of Technology, who were hired as consultants to Standard Oil Company of New Jersey [now ExxonMobil], finally solved this problem with great ingenuity and effort. They developed the “moving bed” catalytic converter, in which the catalyst was itself circulated between two enormous vessels, the reactor and the regenerator.)

Houdry continued his work with catalysts and became particularly fascinated with the catalytic role of enzymes in the human body and the changes in enzyme-assisted processes caused by cancer. About 1950, when the results of early studies of smog in Los Angeles were published, Houdry became concerned about the role of automobile exhaust in air pollution and founded a special company, Oxy-Catalyst, to develop catalytic converters for gasoline engines—an idea ahead of its time. But until lead could be eliminated from gasoline (lead was introduced in the 1920s to raise octane levels), it poisoned any catalyst.

The following taken from Chemical Heritage Foundations Othmer Library Catalog
http://othmerlib.chemheritage.org/search/dArchival+Materials./darchival+materials/-5,-1,0,B/frameset&FF=darchival+materials&5,,16.

Eugene Houdry was born on April 18, 1892 in France. In 1911 he received a degree in mechanical engineering. He worked for his family’s metal working business. In 1930, he moved to the U.S. wher he revolutionized the production of gasoline by developing a process for cracking low-grade fuel into high test gasoline. During WWII, he developed a single-step butane dehydrogenation process for producing synthetic rubber. After WWII, he founded a company entitled Oxy-Catalyst, and shifted his focus to reducing health risks associated with automobile exhaust. He patented the catalytic muffler for automobiles in 1962. He died on July 18, 1962. He was inducted into the National Inventor’s Hall of Fame in 1990.
 
Contributed by A. Mills and Chemical Heritage (http://www.chemheritage.org/classroom/chemach/petroleum/houdry.html)