Type: NACS News

The ACS Catalysis Lectureship for the Advancement of Catalytic Science in Heterogeneous Catalysis recognizes researchers having a recent, significant publication in ACS Catalysis. This year’s winning paper, entitled CO Oxidation on Ir1/TiO2: Resolving Ligand Dynamics and Elementary Reaction Steps (ACS Catal. 2023, 13, 12, 7802–7811) was co-led by Professors Ayman M. Karim (University of Virginia) and Hongliang Xin (Virginia Tech) which reveals the complexity of CO oxidation mechanism on TiO2-supported Ir single atoms.
In their work, kinetic measurements, operando spectroscopy, and quantum-chemical calculations showed that the reaction mechanism has two kinetically relevant steps, an O2 dissociation step and an Eley-Rideal-type step where a gas phase CO reacts with an Ir complex having an unreactive CO bound ligand. Their work showed the ability to identify rate-controlling steps, isolate specific reaction intermediates and identify which ligands participate in the reaction while others are spectators, details which have been traditionally limited to homogeneous catalysts. Additional information about this work and the awardees can be found at ACS Catalysis 2026 Lectureship and Award Winners.
Profs. Karim’s and Xin’s Lectureship will be celebrated during a symposium to be held as part of the Fall 2026 American Chemical Society National Meeting, Chicago, August 23 — 27.
